Light from the sky is a result of the scattering of sunlight, which results in a blue color perceived by the human eye. On a sunny day Rayleigh Scattering gives the sky a blue gradient — dark in the zenith, light near the horizon. Light that comes in from overhead encounters 1/38th of the air mass that light coming along a horizon path encounters. So, fewer particles scatter the zenith sunbeam, and therefore the light remains a darker blue.
The sky can turn a multitude of colors such as red, orange and yellow (especially near sunset or sunrise) and black at night. Scattering effects also partially polarize light from the sky.
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www.wikipedia.org
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